FPFF-L1.1

Fire chemistry: triangle, tetrahedron and heat transfer

FPFF-M1 · Fire science · FPFF-M1-A How fire works, the classes of fire and where ignition comes from on a yacht.

Fire is a chemical reaction with **four requirements**. Remove any one and it stops, which is the whole basis of firefighting.

The elements of fire and explosion

Governing: STCW Table A-VI/1-2, "the elements of fire and explosion (the fire triangle)". Builds on: nothing, start here.

Every technique on the practical course follows from one idea: fire needs certain things, and taking one away puts it out.

The fire triangle

Side What it is Aboard a yacht
Fuel Anything that burns Furnishings, linen, teak, cooking oil, diesel, petrol for tenders and toys, paint stores
Heat Enough energy to reach ignition temperature Galley, laundry, engine exhausts, electrical faults, hot work
Oxygen About 21% of air Always present; forced ventilation adds more

The tetrahedron

Once burning, fuel breaks down and reacts in a chain reaction that keeps generating heat and flammable gases. The fire tetrahedron adds that chain reaction as a fourth face. Some agents, notably dry powder and some clean agents, work mainly by interrupting it.

Four ways to put a fire out

Method Removes Example
Starving Fuel Shut the fuel quick-closing valve; isolate gas; move combustibles away
Smothering Oxygen Fire blanket on a pan; foam over a fuel spill; shut down ventilation; CO2 flooding
Cooling Heat Water jet or spray; boundary cooling
Breaking the chain reaction Chain reaction Dry powder; some gaseous agents

Most real firefighting combines them: shut off the fuel, close the space, cool the boundaries, then attack.

Flammable liquids

Liquids do not burn; their vapour does.

  • Flashpoint: the lowest temperature at which a liquid gives off enough vapour to form an ignitable mixture with air.
  • Auto-ignition temperature: the temperature at which the mixture ignites without an external spark or flame.
  • Flammable limits: the vapour must be within a range of concentration in air. Too lean or too rich will not burn, but a rich mixture becomes flammable as air leaks in.

Petrol has a very low flashpoint, which is why tender and jet-ski fuel is stowed under the special rules of REG Yacht Code Chapter 14.1. Diesel has a much higher one but, as a fine spray from a leaking high-pressure pipe onto a hot exhaust, it ignites readily.

How fire spreads

Mechanism How Shipboard effect
Conduction Through solids Steel decks and bulkheads carry heat into the next space
Convection Hot gases rise and travel Smoke and heat move up stairwells, lift shafts and trunking
Radiation Heat travels in straight lines Ignites nearby materials across an open space
Direct contact Flame touches fuel Spread along furnishings and linings

This is why firefighting includes boundary cooling and checking the spaces above, below and beside the fire.

Products of combustion

Most fire deaths are caused by smoke, not flames. Smoke is hot, blinding and toxic:

  • carbon monoxide: odourless, causes confusion and unconsciousness;
  • carbon dioxide and lack of oxygen;
  • irritant and toxic gases from plastics, foam and synthetic fabrics, which yachts are full of;
  • hydrogen fluoride and heavy-metal particles from lithium-ion batteries (L4.3).

WARNING — Smoke kills first Never enter smoke without breathing apparatus. A few breaths can incapacitate you before you see a flame.

TIP — Backdraught and flashover A closed, oxygen-starved space full of hot gases can ignite violently when a door is opened. Feel doors with the back of your hand before opening, and follow the fire party leader.

Practice questions

5 questions

recall · core

What does the fire tetrahedron add to the fire triangle? (a) Electricity (b) Water vapour (c) Smoke (d) The chemical chain reaction

recall · core

Removing heat from a fire is called what? (a) Inhibiting (b) Starving (c) Cooling (d) Smothering

recall · core

By which heat transfer method does a steel bulkhead carry fire into the next compartment? (a) Convection (b) Radiation (c) Evaporation (d) Conduction

recall · core

What is the flashpoint of a liquid? (a) The lowest temperature at which it gives off enough vapour to form an ignitable mixture (b) The temperature of its flame (c) The temperature at which it ignites without a spark (d) The temperature at which it boils

scenario · core

A fire in the galley is out, but the deckhead of the crew mess above is hot and the paint is blistering. What is happening and what do you do? (a) Nothing; the fire is out (b) Heat is conducting through the deck; report it, check and cool the space above and keep a watch (c) Open all doors to ventilate (d) Paint over it later

Independent study. xplor is not an accredited training provider and awards no certificate or Certificate of Competency. The FPFF certificate of proficiency requires live fire, smoke and breathing apparatus exercises at an MCA-approved (or flag-recognised) training centre, and its five-yearly update cannot be earned on board. AI-drafted content pending subject-matter-expert review.